carboxyphenyl aminohydantoin (3.38 and 3.5 3) and also for nitro furantoin (2. 27 and 2.49) were calculated. In the synthesis of MIPs, the choice o f t he chemical reagents is of pr imary import ...
The cover illustrates a free energy profile of an unusual stepwise mechanism via hydrogen transfer and reductive elimination in the azacycle-directed intermolecular aromatic C(sp2)–H functionalization of Cr(0) Fischer carbene complexes. The rate-determining step is the hydrogen migration, in which the C(sp2)–H bond is effectively activated by the Cr center, leading to the …
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Experimental and theoretical insights into the nature of intermolecular interactions and their effect on optical properties of 1-allyl-4-(1-cyano-2-(4-dialkylaminophenyl)vinyl)pyridin-1-ium bromide salts (I and II) are reported.A comparison of optical properties in solution and in the solid-state of the salts (I and II) with their precursors (Ia and IIa) is made.
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The temperature was set to be 180 °C, 220 °C, 260 °C and the C/F ratio was set to be 0.3, 0.5 and 0.7 on a mass basis. A 3 × 3 factorial design was used for this study, as shown in Fig. 1 . The water to feedstock (W/F) ratio was set to …
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2. Results and discussion. To optimize the potency of 1, systematic structural modifications around the t-butyl phenyl aniline (ring A) (analogs 1–27), urea linker (analogs 28–34), nicotinonitrile (ring C) (analogs 35–61) were performed (Fig. 1B). The optimization was guided by lipophilic ligand efficiency (LipE = pIC 50 − CLogP) to balance potency and lipophilicity …
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We use `xor` for more than one type. The others are only used on `Word64` values. class Xor a where xor :: a -> a -> a instance Xor Word64 where xor (Word64 a b) (Word64 c d) = Word64 (xor a c) (xor b d) instance Xor Word where xor = wordXor instance Xor Int where xor = intXor complement x = 0-1-x (Word64 a b) .|.
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